2021   02   en   p.54-60 E.M. Kerimova, S.N. Mustafaeva, N.Z. Gasanov, К.М. Husеynova, Q.M. Sharifov,
TlGa1-xErxSe2 solid solutions, their electrical and optical properties
 pdf 

ABSTRACT

The complex permittivity, dielectric loss tangent, and conductivity σac of TlGa1-xErxSe2 solid solutions (x = 0; 0.001; 0.005) were studied in the temperature range 150-300 K in an alternating electric field (25-106 Hz). The change in dielectric constant as a function of temperature in the studied crystals is due to the presence of low-frequency relaxation polarization. Conductivity obeys the law σac ~ f 0.8 at frequencies of 102–104 Hz, which, in the studied crystals, indicates the presence of hopping conductivity by states localized near the Fermi level. The parameters of the states localized in the TlGa1-xErxSe2 band gap are estimated. It was shown that an increase in the Er impurity leads to an increase in the density of localized states in TlGaSe2 and a decrease in their energy spread. The optical absorption edge of TlGa1-xErxSe2 crystals was studied, and the temperature dependence of the band gap in them was obtained.

Keywords: solid solutions, complex dielectric permittivity, frequency dispersion, dielectric loss, conductivity, optical absorption edge.
PACS: 72.20.-i ; 78.00.00

DOI:-

Received: 02.06.2021

AUTHORS & AFFILIATIONS

Institute of Physics, National Academy of Sciences of Azerbaijan, Baku, AZ-1143
E-mail: *ngasanov@yandex.ru
REFERENCIES

[1]   D. Müller and H. Hahn: Zur Struktur des TlGaSe2. Z. Anorg. Allg. Chem. 438(1), 1978, 258-272.
[2]   E.M. Kerimova, S.N. Mustafaeva, D.A. Huseinova. Hard radiation detectors on A3B6-based semiconductors and their complex analogues. Proceedings of Eurasia Conf. on nuclear science and its appl., Turkey, 2000, 394.
[3]   S. Johnsen, Z. Liu, J.A. Peters, J.-H. Song, S.C. Peter, C.D. Malliakas, N.K. Cho, H. Jin, A.J. Freeman, B.W. Wessels, M.G. Kanatzidis. Chem. Mater. 23, 2011, 3120-3128.
[4]   E.M. Kerimova. Crystal physics of low-dimensional chalcogenides. Baku, Elm, 2012.
[5]   S. Yang, M. Wu, H. Wang, H. Cai, L. Huang, C. Jiang, S. Tongay. Ultrathin ternary semiconductor TlGaSe2 phototransistors with broad-spectral response. 2D Mater, 4(3), 2017, S1-S6.
[6]   S.N. Mustafaeva, V.A. Aliyev, M.M. Asadov. Physics of the Solid State, 40, 1998, 41-44.
[7]   S.N. Mustafaeva. Journal of Radio Electronics, 5, 2008, 1-11.
[8]   A.U. Sheleg, K.V. Iodkovskaya, N.F. Kurilovich. Physics of the Solid State, 40(7), 1998, 1328-1331.
[9]   S.N. Mustafaeva, M.M. Asadov, A.A. Ismayilov. Applied Physics 3, 2012, 19-23.
[10]  A.Cengiz, Y.M. Chumakov, M. Erdem, Y. Şale, F.A. Mikailzade, M-H.Y. Seyidov. Origin of the optical absorption of TlGaSe2 layered semiconductor in the visible range. Semicond. Sci. Technol. 33, 2018, 075019.
[11]  L.Yu Kharkhalisa, K.E. Glukhova, T.Ya Babuka, M.V. Liakha. Phase Transitions. A Multinational Journal, 2019, 92(5).
[12]  A.M. Panich. J.Phys.: Condensed Matter, 20 (29), 2008, 293202/1-42.
[13]  A.U. Sheleg, V.V. Shevtsova, V.G. Hurtavoy, S.N. Mustafaeva, E.M. Kerimova. Low Temperature X-Ray Investigations of TlInS2, TlGaS2 and TlGaSe2 Single Crystals. Surface. X-ray, synchrotron and neutron studies. 11, 2013, 39–42.
[14]   A.Say, D. Adamenko, O. Gomonnai, I. Roman, I. Martynyuk-Lototska, R. Vlokh. Phase Transitions. A Multinational Journal, 2019, 92(9).
[15]  S.N. Mustafaeva, M.M. Asadov, E.M. Kerimova. Physics of the Solid State, 55(12), 2013, 2466-2470.
[16]  H.D. Hochheimer, E. Gmelin, W. Bauhofer, et al. Z. Phys. B. Condens. Matter, 73, 1988, 257-263.
[17]  N.F. Mott, E.A. Davis. Electronic Processes in Non-Crystalline Materials. Clarendon, Oxford, 1971.