AJP Fizika E
Institute of Physics
Ministry of Science and Education
Republic of Azerbaijan
ISSN 1028-8546
Azerbaijan Journal of Physics
Published from 1995. Registration number: 514, 20 02 1995
Ministry of Press and Information of Azerbaijan Republic
2022 02 en p.10-14 | B. Emdadi2, A. Asimov1,2, F. Tatardar1,2, Graphene-based cathode materials for dye-sensitized solar cells: a review |
ABSTRACT In recent years, color-sensitive solar cells (DSSCs) have gained widespread attention for serving as potentially low-cost alternatives to silicon-based solar cells. In DSSCs, platinum-based materials (Pt) used as counter-electrodes (CEs) show superior catalytic ability than triiodide ion reduction reactions, which are attributed to their excellent catalytic activity and high electrical conductivity. However, in order to achieve cost-effective DSSCs, reasonable efforts have been made to discover alternatives without Pt. Recently, a large number of ground-based catalysts, especially carbon-based materials, have shown high activity, low cost, and good stability, making them attractive candidates for platinum replacement in DSSCs. Recently, inexpensive graphene-based counter (CE) electrodes have been developed that could serve as a potential alternative to expensive platinum-based CEs. In this review article, the development of DSSCs and the properties of graphene are briefly described. Then, the application of graphene-based materials for photo electrodes (transparent electrode, semiconductor layer, and color sensitizer) in DSSCs is discussed in depth. Finally, we have a comprehensive perspective on graphene materials in DSSCs is presented. Keywords: Dye-Sensitized Solar Cells, Ghraphene, Graphene Molecules, Graphene-Carbon Nanotube Components, Solar Cells, Renewable energy. PACS: 65.80 Ck, 61.48 Gh, 63.37 Hk Received: 11.03.2022 AUTHORS & AFFILIATIONS 1. Institute of Physics of Azerbaijan National Academy of Sciences, AZ-1143, 131, H. Javid ave., Baku, Azerbaijan 2. Institute of Physics & Electronic of Khazar University (Neftchilar Campus), AZ-1096, Khazar University 41 Mahsati Str., Baku, Azerbaijan E-mail: Corresponding author: emdadi.babak2021@khazar.org |
REFERENCIES [1] Energy Technology Perspectives 2015, International Energy Agency, Paris, France, 2015. [2] C. Philibert. Solar energy perspectives 2011, Organizations for Economic Co-operation and Development and International Energy Agency, Paris, France 2011. [3] International Technology Roadmap for Photovoltaic (ITRPV). [4] T. Bradford. Solar Revolution: The Economic Transformation of the Global Energy Industry, MIT Press, Cambridge 2006. [5] V. Balzani and N. Armaroli. Energy for a Sustainable World— From the Oil Age to a Sun-Powered Future, Wiley-VCH, Weinheim 2011. [6] Eric Singh, Hari Singh Nalwa. “Graphene-Based Dye-Sensitized Solar Cells: A Review” Sci. Adv. Mater. 2015, Vol. 7, № 10 [7] K.L. Chopra, P.D. Paulson, & V. Dutta. 2004. Thin-film solar cells: An overview, progress in photovoltaics. Res. Appl., 12, 69–92. [8] Michael Grätzel. “Dye-sensitized solar cells”, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Volume 4, Issue 2, 2003, Pages 145-153. [9] Khushboo Sharma, Vinay Sharma, S.S. Sharma. “Dye-Sensitized Solar Cells: Fundamentals and Current Status” Nanoscale Research Letters volume 13, 2018, Article number: 381.v [10] Cole, M. Jacqueline, Pepe, Giulio, Al Bahri, K. Othman, B. Cooper, Christopher. 2019. Cosensitization in Dye-Sensitized Solar Cells. Chemical Reviews, acs. chemrev.8b00632. [11] B. O’Regan, M. Gratzel. 1991. A Low-cost highefficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 353: 737-740. [12] Anders Hagfeldt, Gerrit Boschloo, Licheng Sun, Lars Kloo, and Henrik Pettersson. “Dye-Sensitized Solar Cells” Chem. Rev. 2010, 110, 6595–6663. [13] Di Wei. “Dye Sensitized Solar Cells”, Int. J. Mol. Sci. 2010, 11, 1103-1113. [14] Aslam, Asad; Mehmood, Umer; Arshad, Muhammad Hamza; Ishfaq, Abdulrehman; Zaheer, Junaid; Ul Haq Khan, Anwar; Sufyan, Muhammad. 2020. Dye-sensitized solar cells (DSSCs) as a potential photovoltaic technology for the self-powered internet of things (IoTs) applications. Solar Energy, 207, 874–892. [15] M.-E. Ragoussi, T. Torres. Chem. Commun. 51, 2015, 3957–3972. [16] N.S. Lewis, D.G. Nocera. Proc. Natl. Acad. Sci. U.S.A. 103, 2006. 15729–15735. [17] M.A. Green. Phil. Trans. R. Soc. A 371, 2013, 1–14. [18] M.A. Green, K. Emery, Y. Hishikawa, W. Warta, E.D. Dunlop. Prog. Photovolt: Res. Appl. 21, 2013, 827–837. [19] L.M. Peter, Phil. Trans. R. Soc. A 369, 2011, 1840–1856. [20] P.M. Beaujuge, J.M.J. Fréchet. J. Am. Chem. Soc. 133, 2011, 20009–20029. [21] M. Urbani, M. Grätzel, M.K. Nazeeruddin, T. Torres. Chem. Rev. 114, 2014, 12330–12396. [22] M. Grätzel. Acc. Chem. Res. 42, 2009, 1788–1798. [23] K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, M.I. Katsnelson, I.V. Grigorieva, S.V. Dubonos, and A.A. Firsov. 2D gas of massless Dirac fermions in graphene. Nature 438, 197–200, 2005. [24] A.K. Geim and K. S. Novoselov. The rise of graphene. Nature Mater. 6, 183–191, 2007. [25] A.K. Geim. Graphene: Status and prospects. Science 324, 2009. 1530–1534. [26] Man-Ning Lu, Chin-Yu Chang,Tzu-Chien Wei, Jeng-Yu Lin. “Recent Development of Graphene-Based Cathode Materials for Dye-Sensitized Solar Cells” Volume 2016, |Article ID 4742724. [27] G. Calogero, A. Bartolotta, G. Di Marco, A. Di Carlo, and F. Bonaccorso. “Vegetable-based dye-sensitized solar cells,” Chemical Society Reviews, vol. 44, № 10, pp. 3244–3294, 2015. [28] J.D. Roy-Mayhew, D.J. Bozym, C. Punckt, and I.A. Aksay. “Functionalized graphene as a catalytic counter electrode in dye-sensitized solar cells,” ACS Nano, vol. 4, № 10, pp. 6203–6211, 2010. [29] D.W. Zhang, X.D. Li, H.B. Li et al., “Graphene-based counter electrode for dye-sensitized solar cells,” Carbon 2011, vol. 49, № 15, pp. 5382–5388. |