THERMOPHYSICAL, DIELECTRIC AND CONDUCTIVITY PROPERTIES OF PLASMA-MODIFIED COMPOSITES BASED ON PVDF DISPERSED WITH BaTiO3 PARTICLES
I.S. Ramazanova, G.Kh. Guseynova, U.V. Yusifova, T.D. Ibragimov, A.F. Nuraliyev, F.F. Yahyayev,
2024   03   en   p.20-28

ABSTRACT

The effect of barrier electric discharge plasma on thermophysical, dielectric and conductive properties of PVDF+BaTiO3 based composite has been studied. It is shown that the enthalpy and entropy of melting and solidification decrease sharply when the filler is included, and a relative increase is observed at a concentration of 20%. At the other concentrations, however, except at 10% and 30%, these physical quantities decrease after exposure to barrier electric discharge plasma. This increase is negligible for pure polyvinylidene fluoride but significant for composites. Also the dielectric permittivity increases with increasing concentration. It is shown that the conductivity first increases with increasing filler concentration, reaches a maximum at 20% concentration and then decreases. After exposure to barrier electric discharge plasma, the dielectric permittivity and conductivity decrease.

Keywords: barium titanate, polyvinylidene fluoride, dielectric permittivity; electric conductivity, composite material.
PACS: 77.55.+f , 77.84._s , 77.84.Dy, 77.84.Lf, 81.07.Pr , 82.35.Np

DOI:-

Received: 17.07.2024
Internet publishing: 14.08.2024

AUTHORS & AFFILIATIONS

Institute of Physics Ministry of Science and Education Republic of Azerbaijan, 131 H.Javid ave, Baku, AZ-1143, Azerbaijan
E-mail: irada-sultanakhmedova@rambler.ru

Graphics and Images

                                             

Fig.1-2       Fig.3-4-5-6        Fig.7-8-9-10        Fig.11-12-13-14-15-16

REFERENCIES

[1]   T.D. Ibragimov, I.S. Ramazanova, G.Kh. Guseynova, U.V. Yusifova, A.F. Nuraliyev. Dielectric properties of polyethylene doped with barium titanate particles. AJP Fizika, 2022 28( 1), pp.43-45.
[2]   Rui Li, Zhenhua Zhao, Zixuan Chen, and Jianzhong Pei. Novel BaTiO3/PVDF composites with enhanced electrical properties modified by calcined BaTiO3 ceramic powders. Mater. Express, Vol. 7, № 6, 2017, pp.536-540.
[3]   T.D. Ibragimov, I.S. Ramazanova, G.Kh. Guseynova, U.V. Yusifova, A.F. Nuraliyev. Dielectric and conductivity properties of polyethylene doped with barium titanate particles. UNEC Journal of Engineering and Applied Sciences Vol. 2, № 1, 2022, pp. 5-12
[4]   Novak, M. Steviar, A. Popelka, I. Chodak, J. Mosnacek, M. Spirkova, I. Janigova, A.Kleinova, J. Sedliacik, M. Slouf. Surface Modification of polyethylene by diffuse barrier discharge plasma. J. Polym. Engineering and Sci. 53 (3), 1, 2012, pp.
[5]   W. Kun, L. Jian, R. Chunsheng, W. Dezhen, W. Younian. Surface modification of polyethylene (PE) films using dielectric barrier discharge plasma at atmospheric pressure. J. Plasma Sci. and Technol. 10 (4), 433, 2008.
[6]   J.M. Grace, L.J. Gerenser. Plasma treatment of polymers, J. Dispersion Sci. Technol. 24, 305, 2003.
[7]   S. Guimond, M.R. Wertheimer. Surface degradation and hydrophobic recovery of polyolefins treated by air corona and nitrogen atmospheric pressure glow discharge, J. Appl. Polym. Sci. 94 (3), 1291, 2004.
[8]   L. Parali. The electret effects of crystallized polymer–ferropiezoelectric composite under electric discharge plasma, J. Electrostatics. 76, 89, 2015.
[9]   Novák, G.K. Elyashevichb, I. Chodák, A.S. Olifirenko, M. Števiar, M. Špírková, N. Saprykina, E. Vlasova, A. Kleinová. Polymer matrix of polyethylene porous films functionalized by electrical discharge plasma, European Polym. Journal 44, 2702, 2008.
[10]  F. Arefi-Khonsaria, M. Tatouliana, F. Bretagnola, O. Bouloussab, F. Rondelez. Processing of polymers by plasma technologies, J. Surface & Coatings Technol. 200, 14, 2005. DOI:10.1016/j.surfcoat.2005.02.184
[11]  M. Tahara, N.K. Cuong, Y. Nakashima. Improvement in adhesion of polyethylene by glow-discharge plasma. Surface and Coatings Technol. 174–175, 826, 2003.
[12]  R. Morent, N. De Geyter, T. Jacobs, S. Van Vlierberghe, P. Dubruel, C. Leys, E. Schacht. Plasma-polymerization of HMDSO using an atmospheric Pressure dielectric barrier discharge plasma process Polym. 6 (1), 537, 2009.
[13]   M.A. Kurbanov, V.A. Gol’dade, S.V. Zotov, I. S. Ramazanova, A.F. Nuraliev, F.F. Yakhyaev, U.V. Yusifova, B.G. Khudayarov. Generation of craze-formation centers in polymer films under the action of electric discharge plasma. Technical Physics 63(7), 965 (2018).
[14]  M.A. Kurbanov, I.S. Sultanakhmedova, É.A. Kerimov, Kh.S. Aliev, G.G. Aliev, G.M. Geіdarov. Plasma crystallization of polymer–ferroelectric/piezoelectric ceramic composites and their piezoelectric properties. Physics of the Solid State 51(6), 1223, 2009.